The heteroatom substituted zeolites TS-1, Sn-MFI, Fe-MFI and Zn-MFI, Sn-MEL, Ti-Beta, Sn-MWW have strong Lewis acidity, which can be acted as solid Lewis catalysts and catalyst supports. The Si/M, morphologies, crystal diameters and mesoporous structures of the zeolite products can also be controlled within a certain range, and products can be customized according to the corresponding utilization.